Yoshikawa, Masako & Nakamura, Eizo (2000) Geochemical evolution of the Horoman peridotite complex: Implications for melt extraction, metasomatism, and compositional layering in the mantle, Journal of Geophysical Research, 105, 2879-2901, doi:10.1029/1999JB900344. < 20150914111345-514571 > pub

Map on Earth or stone. Places and analyses are shown.

  • abstract:

    Major and trace element compositions and isotopic ratios of Sr and Nd were determined for bulk rocks and their constituent clinopyroxenes from the Horoman peridotite complex, Japan. Al2O3, CaO, and heavy rare earth elements (HREE) contents of peridotites generally decrease from plagioclase lherzolite through spinel lherzolite to spinel harzburgite, indicating simple melt extraction from a single source. However, the extremely large variations in isotopic (87Sr/86Sr = 0.7019 to 0.7066, εNd = +110 to −10) and trace element compositions ([Ce/Yb]N = 0.006 to 4.0) cannot be explained by a simple melt extraction mechanism. The samples can be divided into two groups: one suite has depleted isotopic and light REE (LREE) characteristics (DP), while the other suite shows enriched isotopic and LREE signatures (EP). Sm‐Nd isotope systematics of whole‐rock DP samples yield an isochron age of 833±78 Ma with an initial 143Nd/144Nd ratio of 0.5119±2, which is identical to the isotopic composition of mid‐ocean ridge basalt (MORB) source mantle at that time. The relationship between MgO and Yb abundances of whole rocks shows that melt extraction was initiated at pressures near the garnet and spinel lherzolite transition. Peridotites that formed at different depths presently occur in close proximity to each other, sometimes within tens of meters. The chemical and isotopic signatures of the EP samples can be explained by mixing between mantle residue and an isotopically and more incompatible element enriched fluid derived from a subducted slab. These observations suggest that the small‐scale compositional layering observed in the complex may have formed in a wedge mantle by water‐enhanced thinning and folding of metasomatized peridotites which had previously developed large‐scale simple stratification as a result of melt extraction beneath a mid‐ocean ridge.

  • doi: 10.1029/1999JB900344
  • modified at 7 h ago
1: 85071914_ICP 2: 62213_ICP 3: YOH B_ICP 4: BZ262_ICP 5: YOH8_ICP 6: BZ146_ICP 7: 62130 8: BZ257_ICP 9: 91063916_ICP 10: BZ143_ICP 11: YOH7_ICP 12: 85072011m_ICP 13: BZ216_ICP 14: HD03_ICP 15: 62127_ICP 16: BZ116_ICP


(a) ICPMS on ICPMS Yokogawa PMS2000
1: 85071914 2: 62213 3: YOH B 4: BZ262 5: YOH8 6: BZ146 7: 62130 8: BZ257 9: 91063916_Sp.L. 10: BZ143 11: YOH 7 12: 85072011m 13: BZ216 14: HD03 15: 62127 16: BZ116


(a) XRF on XRF PANalytical PW2400
(b) Tritration with gravimetry on XRF PANalytical PW2400
1: 91063916_Cpx_core 2: 91063916_Cpx_rim 3: BZ143_Cpx_60 micrometers from rim 4: BZ143_Cpx_145 micrometers from rim 5: BZ143_Cpx_230 micrometers from rim 6: BZ143_Cpx_315 micrometers from rim 7: BZ143_Cpx_435 micrometers from rim 8: BZ143_Cpx_525 micrometers from rim 9: BZ143_Cpx_610 micrometers from rim 10: BZ143_Cpx_695 micrometers from rim 11: YOH7_Cpx_core 12: YOH7_Cpx_rim 13: 85072011m_Cpx_core 14: 85072011m_Cpx_rim 15: BZ216_Cpx_core 16: BZ216_Cpx_rim 17: HD03_Cpx_core 18: HD03_Cpx_rim 19: 62127_Cpx_core


(a) SIMS on SIMS Cameca ims-5f
1: 85071914_SrNd 2: 85071914_Cpx_SrNd 3: 62213_SrNd 4: YOH B_SrNd 5: YOH B_Cpx_SrNd 6: BZ262_SrNd 7: BZ262_Cpx_SrNd 8: YOH8_SrNd 9: YOH8_Cpx_SrNd 10: BZ146_SrNd 11: BZ146_Cpx_SrNd 12: 62130_SrNd 13: BZ257_SrNd 14: BZ257_Cpx_SrNd 15: 91063916_SrNd 16: 91063916_Cpx_SrNd 17: BZ143_SrNd 18: BZ143_Cpx_SrNd 19: YOH7_SrNd 20: YOH7__Cpx_SrNd 21: 85072011m_SrNd 22: 85072011m_Cpx_SrNd 23: BZ116J_SrNd 24: BZ116J-CPx_SrNd 25: HD03_SrNd 26: 62127_SrNd 27: BZ216_SrNd 28: BZ216CPx_SrNd


(a) Sr isotopes_procedures of Yoshikawa and Nakamura (1993) on TIMS Thermo-Fisher MAT261
(b) TIMS on TIMS Thermo-Fisher MAT261
1: 85071914_Cpx_core 2: 85071914_Cpx_rim 3: 62213_Cpx_core 4: 62213_Cpx_rim 5: YOH B_Cpx_core 6: YOH B_Cpx_rim 7: BZ262_Cpx_core 8: BZ262_Cpx_rim 9: YOH8_Cpx_core 10: YOH8_Cpx_rim 11: BZ146_Cpx_core 12: BZ146_Cpx_rim 13: BZ257_Cpx_55 micrometers from rim 14: BZ257_Cpx_135 micrometers from rim 15: BZ257_Cpx_210 micrometers from rim 16: BZ257_Cpx_290 micrometers from rim 17: BZ257_Cpx_385 micrometers from rim 18: BZ257_Cpx_465 micrometers from rim 19: BZ257_Cpx_585 micrometers from rim


(a) SIMS on SIMS Cameca ims-5f
Img 490700 thumb YOH8 < 20140303130924-871699 >pub
  • IGSN: IEDRM00I0
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • quantity (kg): 0.96
  • description: Mount Yoshida section, Horoman peridotite (Plagioclase lherzolite); described in Yoshikawa & Nakamura, 2000
  • modified at 2019-12-05
Tixhr1638305924 thumb YOH 7 < 20151026090009-906343 >pub
  • IGSN: IEDRM00I1
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • quantity (kg): 0.985
  • description: Mount Yoshida section, Horoman peridotite (Spinel lherzolite); described in Yoshikawa & Nakamura, 2000
  • modified at 2019-12-05
Tixhr 1891114326 thumb YOH B < 20151026091318-942668 >pub
  • IGSN: IEDRM00I2
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • quantity (kg): 1.38
  • description: Mount Yoshida section, Horoman peridotite (Plagioclase lherzolite); described in Yoshikawa & Nakamura, 2000
  • modified at 2019-12-05
BZ262 < 20190618095054-345067 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Bozu Stream section, Plagioclase lherzolite
  • modified at 2019-12-05
BZ257 < 20190618110715-594466 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Bozu Stream section, plagioclase lherzolite
  • modified at 2019-12-05
BZ146 < 20190618111930-135348 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Bozu Stream section, plagioclase lherzolite
  • modified at 2019-12-05
BZ143 < 20190618122931-265800 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Bozu Stream section, spinel lherzolite
  • modified at 2019-12-05
62127 < 20190618124845-986950 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Horoman river, harzburgite
  • modified at 2019-12-05
BZ116 < 20190618140151-097795 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Bozu Stream section, harzburgite
  • modified at 2019-06-18
BZ216 < 20190618140936-527962 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Bozu Stream section, harzburgite
  • modified at 2019-06-18
62213 < 20190618131759-454475 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Horoman River, plagioclase lherzolite
  • modified at 2019-12-05
85072011m < 20190618135533-557840 >pub
  • classification: plutonic:ultramafic
  • physical-form: hand specimen
  • status: (lost)
  • description: Horoman River, spinel lherzolite
  • modified at 2019-06-18
Ti hr 835008389 thumb HD03 < 20191202154240-158989 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 0.2
  • modified at 2019-12-05
Ti hr 1505887601 thumb 91063916_Sp.L. < 20191202154710-300649 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 1.2
  • modified at 2019-12-05
Ti hr1538072004 thumb 85071914 < 20191202155030-906970 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 7.2
  • modified at 2019-12-05
Ti hr 1583199975 thumb 62130 < 20191202154851-091006 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 1.8
  • modified at 2019-12-05
name box-type global-id
binder of Geochemical evolution of the Horoman peridotite complex: Implications for melt extraction, metasomatism, and compositional layering in the mantle pub container 20160212165245-864174
name device size global-id
YOH8 pub XRF PANalytical PW2400 1 20190507104428-585080
YOH8 pub XRF PANalytical PW2400 12 20190507103051-947219
YOH B pub XRF PANalytical PW2400 13 20190507103051-840377
YOH B pub XRF PANalytical PW2400 3 20190507104428-839133
YOH 7 pub XRF PANalytical PW2400 11 20190507103053-564655
YOH 7 pub XRF PANalytical PW2400 1 20190507104429-457519
BZ262 pub XRF PANalytical PW2400 13 20190507103051-817797
BZ262 pub XRF PANalytical PW2400 3 20190507104428-588140
BZ257 pub XRF PANalytical PW2400 13 20190507103052-996282
BZ257 pub XRF PANalytical PW2400 3 20190507104429-190341
BZ146 pub XRF PANalytical PW2400 3 20190507104429-709407
BZ146 pub XRF PANalytical PW2400 13 20190507103052-381984
BZ143 pub XRF PANalytical PW2400 12 20190507103053-718841
BZ143 pub XRF PANalytical PW2400 3 20190507104429-940624
62127 pub XRF PANalytical PW2400 3 20190507104429-099194
62127 pub XRF PANalytical PW2400 13 20190507103054-923238
62213 pub XRF PANalytical PW2400 3 20190507104428-717975
62213 pub XRF PANalytical PW2400 13 20190507103050-042152
HD03 pub XRF PANalytical PW2400 1 20190507104429-869442
HD03 pub XRF PANalytical PW2400 12 20190507103054-259925
91062916 pub XRF PANalytical PW2400 12 20190507103053-717226
91062916 pub XRF PANalytical PW2400 1 20190507104429-832281
85071914 pub XRF PANalytical PW2400 13 20190507103050-889709
85071914 pub XRF PANalytical PW2400 3 20190507104428-677095
62130 pub XRF PANalytical PW2400 13 20190507103052-703187
62130 pub XRF PANalytical PW2400 3 20190507104429-236729
62130 pub ICPMS Yokogawa PMS2000 21 20190507110421-982332
62127 pub ICPMS Yokogawa PMS2000 21 20190507110426-287939
YOH 7 pub ICPMS Yokogawa PMS2000 21 20190507110423-938121
BZ143 pub ICPMS Yokogawa PMS2000 21 20190507110423-400133
BZ262 pub ICPMS Yokogawa PMS2000 21 20190507110419-257542
62213 pub ICPMS Yokogawa PMS2000 19 20190507110418-241970
YOH8 pub ICPMS Yokogawa PMS2000 21 20190507110420-562824
BZ116J pub ICPMS Yokogawa PMS2000 21 20190617134943-884298
BZ216 pub ICPMS Yokogawa PMS2000 21 20190617134418-705140
85072011m pub ICPMS Yokogawa PMS2000 21 20190507110424-813509
BZ146 pub ICPMS Yokogawa PMS2000 21 20190507110421-680323
BZ257 pub ICPMS Yokogawa PMS2000 21 20190507110422-169207
91062916 pub ICPMS Yokogawa PMS2000 21 20190507110422-264839
85071914 pub ICPMS Yokogawa PMS2000 21 20190507110418-740315
62213_Sr pub TIMS Thermo-Fisher MAT261 4 20190507160048-644036
HD03 pub ICPMS Yokogawa PMS2000 21 20190507110425-933005
YOH7_Cpx_rim pub SIMS Cameca ims-5f 16 20190507152321-296484
85072011m pub TIMS Thermo-Fisher MAT261 5 20190507160107-848669
BZ216CPx_Sr pub TIMS Thermo-Fisher MAT261 4 20190617151122-508751
62213 pub TIMS Thermo-Fisher MAT261 5 20190507160105-978618
BZ116J pub XRF PANalytical PW2400 3 20190617133900-078141
85072011m_Cpx_core pub TIMS Thermo-Fisher MAT261 4 20190507160051-865074
62213_Cpx_rim pub SIMS Cameca ims-5f 16 20190507120119-610037
YOH 7 pub TIMS Thermo-Fisher MAT261 4 20190507160050-843360
BZ116J pub XRF PANalytical PW2400 11 20190617133000-861970
YOH8_Cpx_rim pub SIMS Cameca ims-5f 16 20190507120122-777933
BZ216_Cpx_core pub SIMS Cameca ims-5f 16 20190507152322-496943
BZ216_Cpx_rim pub SIMS Cameca ims-5f 16 20190507152322-367354
YOH8_Cpx_core pub SIMS Cameca ims-5f 16 20190507120121-749117
BZ143_Cpx_230 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152318-193737
BZ146 pub TIMS Thermo-Fisher MAT261 4 20190507160049-950275
85072011m_Cpx_rim pub SIMS Cameca ims-5f 15 20190507152321-723831
62213_Cpx_core pub SIMS Cameca ims-5f 16 20190507120118-191596
BZ262_Nd pub TIMS Thermo-Fisher MAT261 5 20190507160105-222282
BZ116J_Sr pub TIMS Thermo-Fisher MAT261 4 20190617140922-877727
BZ257_Cpx_465 micrometers from rim pub SIMS Cameca ims-5f 16 20190507120125-641004
YOH B_Cpx_rim pub SIMS Cameca ims-5f 15 20190507120120-391884
YOH 7 pub TIMS Thermo-Fisher MAT261 5 20190507160107-201860
BZ143_Cpx_435 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152319-216903
YOH8_Cpx_core pub TIMS Thermo-Fisher MAT261 4 20190507160049-136954
BZ146_Cpx_rim pub SIMS Cameca ims-5f 15 20190507120123-984287
85072011m_Cpx_core pub SIMS Cameca ims-5f 15 20190507152321-349913
BZ257_Cpx_385 micrometers from rim pub SIMS Cameca ims-5f 15 20190507120125-579351
BZ262_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160105-111780
YOH7_Cpx_core pub TIMS Thermo-Fisher MAT261 4 20190507160050-389812
BZ116J_Nd pub TIMS Thermo-Fisher MAT261 5 20190617140948-280621
YOH B_Cpx_core pub SIMS Cameca ims-5f 15 20190507120119-358367
BZ216_Sr pub TIMS Thermo-Fisher MAT261 4 20190617142104-907969
BZ116J-CPx_Sr pub TIMS Thermo-Fisher MAT261 4 20190617141550-750468
YOH8 pub TIMS Thermo-Fisher MAT261 5 20190507160106-649438
BZ257_Cpx_290 micrometers from rim pub SIMS Cameca ims-5f 16 20190507120124-470250
YOH B_Cpx_core pub TIMS Thermo-Fisher MAT261 2 20190507160049-512373
YOH7_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160107-376589
BZ143_Cpx_610 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152319-489107
BZ146_Cpx_core pub SIMS Cameca ims-5f 15 20190507120122-391254
BZ262_Cpx_rim pub SIMS Cameca ims-5f 16 20190507120120-720272
85072011m pub XRF PANalytical PW2400 13 20190507103053-758869
YOH B pub ICPMS Yokogawa PMS2000 20 20190507110419-126951
BZ216_Nd pub TIMS Thermo-Fisher MAT261 5 20190617142115-774004
BZ216CPx_Nd pub TIMS Thermo-Fisher MAT261 5 20190617151132-127228
BZ257 pub TIMS Thermo-Fisher MAT261 4 20190507160050-672214
BZ116J-CPx_Nd pub TIMS Thermo-Fisher MAT261 3 20190617141606-870990
YOH B pub TIMS Thermo-Fisher MAT261 4 20190507160049-500435
BZ257_Cpx_210 micrometers from rim pub SIMS Cameca ims-5f 16 20190507120124-817614
YOH8 pub TIMS Thermo-Fisher MAT261 4 20190507160049-685914
62127_Cpx_core pub SIMS Cameca ims-5f 16 20190507152323-739400
BZ262_Cpx_core pub SIMS Cameca ims-5f 16 20190507120120-907611
85072011m_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160107-185886
BZ146_Cpx_core pub TIMS Thermo-Fisher MAT261 4 20190507160049-645207
BZ143_Cpx_145 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152317-130309
BZ257 pub TIMS Thermo-Fisher MAT261 5 20190507160106-922137
BZ216 pub XRF PANalytical PW2400 13 20190617131757-150848
85072011m pub XRF PANalytical PW2400 3 20190507104429-979155
BZ143_Cpx_315 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152318-159175
YOH B pub TIMS Thermo-Fisher MAT261 5 20190507160105-954815
62127 pub TIMS Thermo-Fisher MAT261 4 20190507160051-322659
BZ257_Cpx_135 micrometers from rim pub SIMS Cameca ims-5f 16 20190507120124-538544
YOH8_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160106-074361
BZ146 pub TIMS Thermo-Fisher MAT261 5 20190507160106-613558
BZ262_Sr pub TIMS Thermo-Fisher MAT261 4 20190507160049-278265
BZ216 pub XRF PANalytical PW2400 3 20190617132611-915393
BZ262_Cpx_core pub TIMS Thermo-Fisher MAT261 4 20190507160049-047048
BZ257_Cpx_55 micrometers from rim pub SIMS Cameca ims-5f 16 20190507120123-170881
BZ146_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160106-943105
YOH7_Cpx_core pub SIMS Cameca ims-5f 16 20190507152320-988229
YOH B_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160105-112366
BZ143_Cpx_525 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152319-696373
85072011m pub TIMS Thermo-Fisher MAT261 4 20190507160050-983446
62127_Nd pub TIMS Thermo-Fisher MAT261 5 20190507160108-131120
BZ143_Cpx_695 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152320-511147
BZ257_Cpx_55 micrometers from rim pub TIMS Thermo-Fisher MAT261 4 20190507160050-685023
BZ143_Cpx_60 micrometers from rim pub SIMS Cameca ims-5f 16 20190507152317-125038
BZ257_Cpx_55 micrometers from rim pub TIMS Thermo-Fisher MAT261 5 20190507160106-870166
BZ143 pub TIMS Thermo-Fisher MAT261 4 20190507160050-936081
BZ143_Cpx_60 micrometers from rim pub TIMS Thermo-Fisher MAT261 4 20190507160050-073037
BZ143 pub TIMS Thermo-Fisher MAT261 5 20190507160107-181961
BZ257_Cpx_585 micrometers from rim pub SIMS Cameca ims-5f 16 20190507120126-693215
BZ143_Cpx_60 micrometers from rim pub TIMS Thermo-Fisher MAT261 5 20190507160107-611025
62130 pub TIMS Thermo-Fisher MAT261 5 20190507160106-805696
62130 pub TIMS Thermo-Fisher MAT261 4 20190507160049-571142
85071914_Cpx_rim pub SIMS Cameca ims-5f 16 20190507120118-973375
85071914_Cpx_core pub TIMS Thermo-Fisher MAT261 4 20190507160048-382819
85071914_Sr pub TIMS Thermo-Fisher MAT261 4 20190507160048-308927
85071914 pub TIMS Thermo-Fisher MAT261 5 20190507160105-832326
85071914_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160105-949058
85071914_Cpx_core pub SIMS Cameca ims-5f 16 20191205135930-449944
91063916 pub TIMS Thermo-Fisher MAT261 4 20190507160050-316506
91063916_Cpx_rim pub SIMS Cameca ims-5f 16 20190507152317-682368
91063916_Cpx_core pub SIMS Cameca ims-5f 16 20190507152316-459964
91063916_Cpx_core pub TIMS Thermo-Fisher MAT261 4 20190507160050-173823
91063916_Cpx_core pub TIMS Thermo-Fisher MAT261 5 20190507160106-158783
91063916 pub TIMS Thermo-Fisher MAT261 5 20190507160106-973727
HD03_Cpx_core pub SIMS Cameca ims-5f 16 20190507152323-534916
HD03_Cpx_rim pub SIMS Cameca ims-5f 16 20190507152323-316062
HD03 pub TIMS Thermo-Fisher MAT261 4 20190507160051-218322
HD03 pub TIMS Thermo-Fisher MAT261 5 20190507160107-317797
name spots global-id
caption ID rowname stone
Table 2. Whole-rock trace element composition in the Horoman peridotites obtained by ICP-MS pub 20190513110902-122056 trace (Yoshikawa et al., 2000) 16
Table 1.Major element compositions of peridotites in the Horoman peridotite complex pub 20190513110643-144298 major (Yoshikawa et al., 2000) 16
Table 3. Trace element compositions of Clinopyroxenes from Spinel lherzolites and Spinel Harzburgites obtained by Ion Microprobe pub 20190513112633-099012 trace_Cpx Spl lehr (Yoshikawa et al., 2000) 19
Table 4. Elemental and isotopic analyses of whole rocks and clinopyroxenes pub 20190513113309-632574 Sr-Nd isotopes (Yoshikawa et al., 2000) 28
Table 3. Trace element compositions of Clinopyroxenes from Plagioclase lherzolites obtained by Ion Microprobe pub 20191205141046-932118 trace_Cpx Pl lehr (Yoshikawa et al., 2000) 19
manual
  • name
  • Yoshikawa, Masako
  • Nakamura, Eizo