Yamakawa, Akane et al. (2009) Chemical Separation and Mass Spectrometry of Cr, Fe, Ni, Zn, and Cu in Terrestrial and Extraterrestrial Materials Using Thermal Ionization Mass Spectrometry, Analytical Chemistry, 81, 9787–9794, doi: 10.1021/ac901762a. < 20100403102859589.admin > pub

Map on Earth or stone. Places and analyses are shown.

  • abstract:

    A sequential chemical separation technique for Cr, Fe, Ni, Zn, and Cu in terrestrial and extraterrestrial silicate rocks was developed for precise and accurate determination of elemental concentration by the isotope dilution method (ID). The technique uses a combination of cation−anion exchange chromatography and Eichrom nickel specific resin. The method was tested using a variety of matrixes including bulk meteorite (Allende), terrestrial peridotite (JP-1), and basalt (JB-1b). Concentrations of each element was determined by thermal ionization mass spectrometry (TIMS) using W filaments and a Si−B−Al type activator for Cr, Fe, Ni, and Zn and a Re filament and silicic acid−H3PO4 activator for Cu. The method can be used to precisely determine the concentrations of these elements in very small silicate samples, including meteorites, geochemical reference samples, and mineral standards for microprobe analysis. Furthermore, the Cr mass spectrometry procedure developed in this study can be extended to determine the isotopic ratios of 53Cr/52Cr and 54Cr/52Cr with precision of ∼0.05ε and ∼0.10ε (1ε = 0.01%), respectively, enabling cosmochemical applications such as high precision Mn−Cr chronology and investigation of nucleosynthetic isotopic anomalies in meteorites.

  • doi: 10.1021/ac901762a
  • modified at 16 h ago


(a) TIMS on TIMS Thermo-Fisher Triton


(a) TIMS on TIMS Thermo-Fisher MAT262
Tixhr 1512897544 thumb JB-1b < 20160921102320-366434 >pub
  • classification: volcanic:basaltic
  • physical-form: powder
  • status: (unknown)
  • description: Geological Survey of Japan silicate reference material - basalt; split 2, position 244
  • modified at 2020-04-24
Tixhr 854746915 thumb JP-1 < 20190301111946-454924 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 12.8
  • description: Harzburgite, GSJ; split 10, position 84
  • modified at 2020-04-24
20071212 13 thumb Allende-12 < 20071216135000.en >pub
  • classification: chondrite:carbonaceous
  • physical-form: aliquot
  • quantity (g): 0.51212
  • description: Original weight: unknown; Price: unknown; The specimen was provided by the Smithsonian Institution (Split 1, Position 23, 3529).
  • modified at 2020-05-01
20071213 1 thumb Allende-13 < 20071216135144.en >pub
  • classification: chondrite:carbonaceous
  • physical-form: aliquot
  • status: (unknown)
  • description: Original weight: unknown; Price: unknown; PML-Allende standard \#1. Calibrated for Rb-Sr, Sm-Nd by Intern2006 (Angela).
  • modified at 2020-05-01
name box-type global-id
binder of Chemical Separation and Mass Spectrometry of Cr, Fe, Ni, Zn, and Cu in Terrestrial and Extraterrestrial Materials Using Thermal Ionization Mass Spectrometry pub container 20200130104936-862985
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JB-1b_W-Sb-Mo pub ICPMS Yokogawa PMS2000 3 20191008113359-268888
ref-gl-jb1 pub Q-ICPMS Agilent 7500cs 51 20170302124532-058671
JB-1b_B pub ICPMS Yokogawa PMS2000 1 20191007144034-924404
JB-1b pub ICPMS Yokogawa PMS2000 22 20191008091432-377866
JB-1b_TiO2 pub HR-ICPMS Finningan, Element 1 20191008134323-810540
JB-1b_FeO pub 1 20191009140049-796572
JB-1b_Hf pub MC-ICP-MS Finnigan, Neptune 2 20191023150858-204878
JB-1b_d66Zn pub ICPMS Thermo-Fisher Neptune 1 20191003102339-884309
JB-1b_d56Fe pub ICPMS Thermo-Fisher Neptune 1 20191003113551-779082
JB-1b_Ni-Co-Fe-Mn-Cr pub ICPMS Thermo-Fisher Neptune 5 20191003145531-354097
JB-1b_Cr-Ni-Cu-Zn pub HR-ICPMS Finningan, Element 4 20191009100320-175701
JB-1b_Ta-Hf-Nb-Zr pub ICPMS Yokogawa PMS2000 4 20191008105612-912690
JB-1b_S pub HR-ICPMS Finningan, Element 1 20191008141042-854799
JB-1b pub MC-ICP-MS Finnigan, Neptune 1 20191219094725-789741
JB-1b_Cr-Fe-Ni-Cu-Zn pub TIMS Thermo-Fisher MAT262 5 20200130113405-220663
ref-gl-jp1 pub Q-ICPMS Agilent 7500cs 50 20170302124611-535452
JP-1 pub ICPMS Yokogawa PMS2000 22 20191008091429-416093
JP-1_Os-Pt pub ICPMS Thermo-Fisher Element XR 6 20190315111352-886503
JP-1_Re-Os pub TIMS Thermo-Fisher Triton 2 20190313154241-671749
JP-1_TiO2 pub HR-ICPMS Finningan, Element 1 20191008134323-872493
JP-1_FeO pub 1 20191009142516-474524
JP-1 pub ICPMS Yokogawa PMS2000 3 20191008113359-201393
JP-1 pub MC-ICP-MS Finnigan, Neptune 2 20191023150858-436623
JP-1_Li pub ICPMS Yokogawa PMS2000 1 20191015113423-515310
JP-1_Bi-Tl-In-Cd pub Q-ICPMS Agilent 7500cs 4 20191002151233-330475
JP-1_d66Zn pub ICPMS Thermo-Fisher Neptune 1 20191003102339-458610
JP-1_d56Fe pub ICPMS Thermo-Fisher Neptune 1 20191003113551-906961
JP-1_Ni-Co-Fe-Mn-Cr pub ICPMS Thermo-Fisher Neptune 5 20191003145531-083716
JP-1_Ge-As-Se-Te pub Q-ICPMS Agilent 7500cs 4 20191004111800-014469
JP-1_TE-Max2006 pub Q-ICPMS Agilent 7500cs 42 20191021092408-322359
JP-1_Pb-Kuritani2006 pub TIMS Thermo-Fisher MAT261 4 20191021120207-324046
JP-1 pub ICPMS Yokogawa PMS2000 4 20191008105613-631359
JP-1_S pub HR-ICPMS Finningan, Element 1 20191008141042-456644
JP-1_Cr-Ni-Cu-Zn pub HR-ICPMS Finningan, Element 4 20191009100319-996060
JP-1_Pb pub TIMS Thermo-Fisher MAT261 3 20191009104304-125212
JP-1_S (Max, 2012) pub ICPMS Thermo-Fisher Neptune 1 20191223153718-288546
JP-1_Cr-Fe-Ni-Cu-Zn pub TIMS Thermo-Fisher MAT262 5 20200130113406-594443
JP-1_Hf pub MC-ICP-MS Finnigan, Neptune 4 20200130145207-079936
JP-1_Pb pub MC-ICP-MS Finnigan, Neptune 3 20200130150729-784131
JP-1_d7Li pub TIMS Thermo-Fisher MAT261 1 20200210103648-262084
Allende_B pub ICPMS Yokogawa PMS2000 1 20191007144654-469588
Allende average pub XRF PANalytical PW2400 9 20190205122616-321995
Allende average pub Shimadzu AA6200 2 20190205122856-619565
Allende_Smithsonian pub ICPMS Yokogawa PMS2000 22 20191008091438-103352
Allende_W-Sb-Mo pub ICPMS Yokogawa PMS2000 3 20191008113359-711249
Allende_Re-Os pub TIMS Thermo-Fisher MAT262 4 20191011102909-774067
Allende-12_Li pub ICPMS Yokogawa PMS2000 1 20191015113423-683939
Allende_Cr-Ni-Cu-Zn pub HR-ICPMS Finningan, Element 4 20191009100320-196967
Allende_Zr-Nb-Hf-Ta pub ICPMS Yokogawa PMS2000 4 20191008105613-887464
Allende_S (Max, 2012) pub ICPMS Thermo-Fisher Neptune 1 20191223154313-304810
Allende-12_Cr-Fe-Ni-Cu-Zn pub TIMS Thermo-Fisher MAT262 5 20200130113406-116770
Allende-12_eCr pub TIMS Thermo-Fisher Triton 2 20200130115748-829002
SM-Allende_d7Li pub TIMS Thermo-Fisher MAT261 2 20200210101024-869245
Allende average_S pub ICPMS Thermo-Fisher Element XR 1 20190205122059-750799
Allende average_K-Na pub Shimadzu AA6200 2 20190205121955-167609
Allende average_Cl-F pub 761 COMPACT IC 2 20190205122300-370398
Allende average_C pub Thermo Scientific MAT253 1 20190205122205-913204
Allende-13_major pub XRF PANalytical PW2400 11 20131217183156-084379
Allende-PML07_Cr-Fe-Ni-Cu-Zn pub TIMS Thermo-Fisher MAT262 5 20200130113406-823705
Allende-1_Li pub ICPMS Yokogawa PMS2000 1 20191015113423-099440
Allende-1_Sm-Nd pub TIMS Thermo-Fisher MAT261 4 20191011100818-363094
Allende-1_Rb-Sr pub TIMS Thermo-Fisher MAT261 4 20191011100544-271489
Allende-1_Li pub TIMS Thermo-Fisher MAT261 2 20191011094744-904342
Allende-1_Pb pub TIMS Thermo-Fisher MAT261 3 20191011093735-191297
Allende-1_B pub TIMS Thermo-Fisher MAT261 2 20191011092448-714212
Allende-2_Li pub ICPMS Yokogawa PMS2000 1 20191015113423-682201
Allende-2_Sm-Nd pub TIMS Thermo-Fisher MAT261 4 20191011101142-300899
Allende-2_Rb-Sr pub TIMS Thermo-Fisher MAT261 4 20191011101006-857792
Allende-2_Li pub TIMS Thermo-Fisher MAT261 2 20191011095536-404092
Allende-2_Pb pub TIMS Thermo-Fisher MAT261 3 20191011093837-153301
Allende-2_B pub TIMS Thermo-Fisher MAT261 2 20191011092602-927943
Allende-3_B pub TIMS Thermo-Fisher MAT261 2 20191011092717-597128
PML-Allende1_dLi pub TIMS Thermo-Fisher MAT261 2 20200210101451-549925
PML-Allende2_d7Li pub TIMS Thermo-Fisher MAT261 2 20200210101900-738321
name spots global-id
caption ID assembly stone
Table 3. Cr Isotopic Signatures of Allende Reference Powder from the Smithsonian Institution pub 20200130120151-328392 eCr (Yamakawa et al., 2009) 1
Table 2. Summary of Cr, Fe, Ni, Cu, and Zn Concentrations in JB-1b, JP-1, and Allende pub 20200130113610-803828 Cr-Fe-Ni-Cu-Zn (Yamakawa et al., 2009) 4
manual
  • name
  • Yamakawa, Akane
  • Yamashita, Katsuyuki
  • Makishima, Akio
  • Nakamura, E.