Nagender Nath, B. et al. (2009) Comprehensive analysis for major, minor and trace element contents and Sr-Nd-Pb-Hf isotope ratios in sediment reference materials, JSd-1 and MAG-1, Geochemical Journal, 43, 207-216, doi: 10.2343/geochemj.1.0018. < 20100403102548664.admin > pub

Map on Earth or stone. Places and analyses are shown.

  • abstract:

    In view of the requirement of a well-characterized and easily available aquatic sediment reference material, a comprehensive analysis comprising of fifty major, minor and trace elements as well as Sr–Nd–Pb–Hf isotopes were carried out in the stream sediment reference material, JSd-1, issued by the Geological Survey of Japan. The data for marine sediment reference material, MAG-1, issued by U.S. Geological Survey is also obtained for comparison. The elements were divided into two groups: Group I and Group II. Elements in Group I form stable soluble ions in HNO3; and those in Group II form soluble oxo- and fluoro-complexes in HF, such as Zr, Nb, Hf, Ta, etc. For Group I, the sample was decomposed with HF ina tetra fluoro ethylene (TFE) bomb at 245°C for 96 hrs with Mg addition. The elemental concentration was measured by quadrupole type inductively coupled plasma source mass spectrometry (ICP-QMS) and sector field type ICP-MS (ICP-SFMS) using isotope dilution-internal standardization (ID-IS) methods. The aliquot of the sample solution was passed through 3-step column chemistry for isotope ratio determination of Pb by multiple collector (MC) ICP-MS and thermalionization mass spectrometry (TIMS), and Sr and Nd by TIMS. For Group II elements, the sample was decomposed withHF in a TFE bomb with the same time and temperature settings. Zr, Mo, Sn, Sb and Hf were determined by ID, and Nb and Ta by ID-IS using ICP-QMS. The original JSd-1 powder showed heterogeneity for Group II elements, indicating insufficient pulverization and distribution. Thus, we further pulverized the powder and measured the concentration, which showed improved homogeneity. The aliquot for the re-pulverized powder was passed through 2-step column chemistry, and the Hf isotope ratio was determined by MC-ICP-MS. Thus a new data on the trace elements as well as Sr–Nd–Pb–Hf isotope ratios is provided for JSd-1 and MAG-1 in this paper.

  • doi: 10.2343/geochemj.1.0018
  • modified at 12 h ago


(a) Q-ICP-MS_procedures of Makishima and Nakamura (1997, 1999, 2006) on Q-ICPMS Agilent 7500cs
(b) HR-ICPMS on HR-ICPMS Finningan, Element


(a) Pb isotopes_procedures of Makishima et al., (2007) on MC-ICP-MS Finnigan, Neptune


(a) Hf isotopes_procedures of Lu et al. (2007) on MC-ICP-MS Finnigan, Neptune


(a) Pb isotopes_procedures of Kuritani and Nakamura (2002, 2003) on TIMS Thermo-Fisher MAT261


(a) Q-ICP-MS_procedures of Lu et al. (2007) on Q-ICPMS Agilent 7500cs
Tixhr 2054272387 thumb ref JSd-1 < 20180405163001-995930 >pub
  • classification: sedimentary
  • physical-form: powder
  • quantity (g): 60.17
  • description: Issued by the Geological Survey of Japan (GSJ)
  • modified at 2020-03-26
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ref JSd-1-#6 pub Q-ICPMS Agilent 7500cs 27 20200128142412-501787
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ref JSd-1-average pub Q-ICPMS Agilent 7500cs 27 20200128142413-155697
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ref JSd-1-#5 pub Q-ICPMS Agilent 7500cs 27 20200128142411-926257
ref JSd-1-#3 pub Q-ICPMS Agilent 7500cs 27 20200128142410-310552
ref JSd-1-#4 pub Q-ICPMS Agilent 7500cs 27 20200128142411-189636
ref JSd-1-#1 pub HR-ICPMS Finningan, Element 14 20200128142423-542669
ref JSd-1-#2 pub HR-ICPMS Finningan, Element 14 20200128142423-431621
ref JSd-1-#3 pub HR-ICPMS Finningan, Element 14 20200128142424-012878
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ref JSd-1-#6 pub HR-ICPMS Finningan, Element 14 20200128142425-277222
ref JSd-1-#3 pub XRF PANalytical PW2400 13 20200127133337-674394
ref JSd-1-#4 pub XRF PANalytical PW2400 12 20200127133337-469916
ref JSd-1-#2 pub XRF PANalytical PW2400 13 20200127133337-819751
ref JSd-1-#5 pub XRF PANalytical PW2400 12 20200127133338-419964
ref JSd-1-#1 pub XRF PANalytical PW2400 13 20200127133336-454674
JSd-1 pub TIMS Thermo-Fisher Triton 1 20200127094855-325016
JSd-1 pub XRF PANalytical PW2400 13 20200127131702-952648
ref JSd-1-#1 pub Q-ICPMS Agilent 7500cs 7 20200129093118-648136
ref JSd-1-#2 pub Q-ICPMS Agilent 7500cs 7 20200129093119-379811
ref JSd-1-#3 pub Q-ICPMS Agilent 7500cs 7 20200129093119-407212
ref JSd-1-#4 pub Q-ICPMS Agilent 7500cs 7 20200129093120-467321
ref JSd-1-#5 pub Q-ICPMS Agilent 7500cs 7 20200129093120-599284
ref JSd-1-average pub Q-ICPMS Agilent 7500cs 7 20200129093120-790155
ref JSd-1-#1 pub MC-ICP-MS Finnigan, Neptune 1 20200129103725-152281
ref JSd-1-#1 pub TIMS Thermo-Fisher Triton 1 20200129102744-187629
ref JSd-1-#1 pub TIMS Thermo-Fisher MAT262 1 20200129101958-978973
ref JSd-1-#1 pub TIMS Thermo-Fisher MAT261 3 20200129101228-581086
ref JSd-1-#1 pub MC-ICP-MS Finnigan, Neptune 3 20200129094225-887574
ref JSd-1-#2 pub MC-ICP-MS Finnigan, Neptune 1 20200129103725-168996
ref JSd-1-#2 pub TIMS Thermo-Fisher Triton 1 20200129102745-054366
ref JSd-1-#2 pub TIMS Thermo-Fisher MAT262 1 20200129101958-717229
ref JSd-1-#2 pub TIMS Thermo-Fisher MAT261 3 20200129101228-939470
ref JSd-1-#2 pub MC-ICP-MS Finnigan, Neptune 3 20200129094225-317930
ref JSd-1-#3 pub MC-ICP-MS Finnigan, Neptune 1 20200129103725-899515
ref JSd-1-#3 pub TIMS Thermo-Fisher Triton 1 20200129102745-826344
ref JSd-1-#3 pub TIMS Thermo-Fisher MAT262 1 20200129101958-502401
ref JSd-1-#3 pub TIMS Thermo-Fisher MAT261 3 20200129101228-660550
ref JSd-1-#3 pub MC-ICP-MS Finnigan, Neptune 3 20200129094225-269827
ref JSd-1-#4 pub MC-ICP-MS Finnigan, Neptune 1 20200129103725-971712
ref JSd-1-#4 pub TIMS Thermo-Fisher Triton 1 20200129102745-502705
ref JSd-1-#4 pub TIMS Thermo-Fisher MAT262 1 20200129101958-398413
ref JSd-1-#4 pub TIMS Thermo-Fisher MAT261 3 20200129101228-195314
ref JSd-1-#4 pub MC-ICP-MS Finnigan, Neptune 3 20200129094225-488616
ref JSd-1-#5 pub MC-ICP-MS Finnigan, Neptune 1 20200129103725-826037
ref JSd-1-#5 pub TIMS Thermo-Fisher MAT262 1 20200129101958-026042
ref JSd-1-#5 pub TIMS Thermo-Fisher MAT261 3 20200129101228-384751
ref JSd-1-#5 pub MC-ICP-MS Finnigan, Neptune 3 20200129094225-762410
ref JSd-1-#6 pub MC-ICP-MS Finnigan, Neptune 1 20200129103726-547353
ref JSd-1-average pub MC-ICP-MS Finnigan, Neptune 1 20200129103726-302331
ref JSd-1-average pub TIMS Thermo-Fisher MAT262 1 20200129101958-660071
ref JSd-1-average pub TIMS Thermo-Fisher MAT261 3 20200129101228-920536
ref JSd-1-average pub MC-ICP-MS Finnigan, Neptune 3 20200129094225-148845
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caption ID assembly stone
Table 2. Concentration of Group I elements in JSd-1 by ICP-MS pub 20200128143548-347377 trace-1 (Nagender et al., 2009) 7
Table 4a. Pb isotope ratios of JSd-1 by DS-MC-ICP-MS pub 20200129094300-350375 lead 6
Table 7. Hf isotope ratios of JSd-1 by MC-ICP-MS pub 20200129103843-409535 Hf (Nagender et al., 2009) 7
Table 6. Nd isotope ratios of JSd-1 by TIMS pub 20200129102724-194489 Nd (Nagender et al., 2009) 5
Table 4b. Pb isotope ratios of JSd-1 by DS-TIMS pub 20200129101006-758399 lead 6
Table 5. Sr isotope ratios of JSd-1 by TIMS pub 20200129102256-455122 strontium 6
Table 1. Major element composition of JSd-1 by XRF pub 20200127132234-828207 major (Nagender et al., 2009) 6
Table 3. Concentration for Group II elements in JSd-1 by ICP-MS pub 20200129093052-621437 trace-2 (Nagender et al., 2009) 6
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  • name
  • Nagender Nath, B.
  • Makishima, Akio
  • Noordmann, J.
  • Tanaka, Ryoji
  • Nakamura, E.