A new separation method of Ti from silicate materials is presented that is suitable for the determination of
natural Ti isotope variations using multi-collector inductively coupled plasma source mass spectrometry (MC-
ICP-MS). This method makes possible for the first time the separation of Ti from natural materials, with high
purity, high recovery and no introduction of artificial mass fractionation. Following sample decomposition
using HF, Ti is separated using a three-column procedure. In the first column using an anion-exchange resin,
AG 1X8, major elements and the majority of trace elements are separated. In the second column, after
eliminating F- by evaporation with HClO4 and re-dissolution with H2O2–HNO3 , Ti is separated from Zr and Hf using a liquid–liquid extraction resin, U/TEVA. In the third column, which is the same as the first column, trace amounts of Al and P are further removed. Recovery yields were almost unity, and no Ti isotope
fractionation occurred from the overall chemical processing. The reproducibilities (2s) of the Ti isotope ratio measurement for a meteorite (eucrite) and a lamproite were < 0.5ε for ε47Ti, ε48Ti and ε49Ti, and < 1ε for ε50Ti, which were comparable to those for the pure Ti standard solution.
@article{20200212104042-906860,
author = "Makishima, Akio and Zhu, Xiang-Kun and Belshawl, Nick S. and O'Nions, R.Keith",
title = "Separation of titanium from silicates for isotopic ratio determination using multiple collector ICP-MS",
journal = "Journal of Analytical and Atomic Spectrometry",
year = "2002",
number = "10",
volume = "17",
pages = "1290-1294",
doi = "10.1039/B204349A",
}
caption | ID | rowname | stone | ||
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Table 3 Replicates of natural silicate samples pub | 20200212110917-889259 | Ti is. (Max et al., 2002) | 4 | ||