Akio Makishima et al. (2010) Precise determination of Cr, Mn, Fe, Co and Ni concentration by an isotope dilution-internal standardization method employing high resolution MC-ICP-MS, Chemical Geology, 274, 82-86, doi:10.1016/j.chemgeo.2010.03.018. < 20191003142257-739981 > pub

Map on Earth or stone. Places and analyses are shown.

  • abstract:

    A new determination method for Cr, Mn, Fe, Co and Ni in silicate samples by an isotope dilution–internal standardization method (ID–IS)–high resolution (HR)–MC–ICP–MS has been developed. A silicate sample is dissolved into solution, and a Cr-spike solution is added into an aliquot of the sample solution. Then the solution is introduced into HR–MC–ICP–MS without chemical separation. Concentration of Cr is determined by ID, and those of Mn, Fe, Co and Ni are by ID–IS. Matrix effects were examined in detail, and negligible down to a dilution factor (DF; the weight of the sample solution over that of the sample in the solution) of ∼ 3000 for basalt, and ∼ 104 for peridotite and chondrite within an error range of ± 1%. ID–IS–HR–MC–ICP–MS showed intermediate precision of ∼ 1% for basalt and chondrite, which is comparable to ID–TIMS for Cr, Fe and Ni, and > 10 times better than HR–ICP–MS, suggesting that this method is suitable for precise Mn–Cr and Fe–Ni chronometers.

  • doi: 10.1016/j.chemgeo.2010.03.018
  • modified at 13 h ago
1: JB-1b 2: JP-1 3: Allende (T)


(a) HR-ICPMS on ICPMS Thermo-Fisher Neptune
Tixhr 1512897544 thumb JB-1b < 20160921102320-366434 >pub
  • classification: volcanic:basaltic
  • physical-form: powder
  • status: (unknown)
  • description: Geological Survey of Japan silicate reference material - basalt; split 2, position 244
  • modified at 2020-04-24
Tixhr 854746915 thumb JP-1 < 20190301111946-454924 >pub
  • classification: plutonic:ultramafic
  • physical-form: powder
  • quantity (g): 12.8
  • description: Harzburgite, GSJ; split 10, position 84
  • modified at 2020-05-15
Img 6464@dc0ecf9fb3de4587b5e76f7 thumb Allende (T) < 20120627095122-376-076 >pub
  • classification: chondrite:carbonaceous
  • physical-form: powder
  • quantity (g): 0.11659
  • modified at 2020-05-15
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JB-1b_W-Sb-Mo pub ICPMS Yokogawa PMS2000 3 20191008113359-268888
ref-gl-jb1 pub Q-ICPMS Agilent 7500cs 51 20170302124532-058671
JB-1b_B pub ICPMS Yokogawa PMS2000 1 20191007144034-924404
JB-1b pub ICPMS Yokogawa PMS2000 22 20191008091432-377866
JB-1b_TiO2 pub HR-ICPMS Finningan, Element 1 20191008134323-810540
JB-1b_FeO pub 1 20191009140049-796572
JB-1b_Hf pub MC-ICP-MS Finnigan, Neptune 2 20191023150858-204878
JB-1b_d66Zn pub ICPMS Thermo-Fisher Neptune 1 20191003102339-884309
JB-1b_d56Fe pub ICPMS Thermo-Fisher Neptune 1 20191003113551-779082
JB-1b_Ni-Co-Fe-Mn-Cr pub ICPMS Thermo-Fisher Neptune 5 20191003145531-354097
JB-1b_Cr-Ni-Cu-Zn pub HR-ICPMS Finningan, Element 4 20191009100320-175701
JB-1b_Ta-Hf-Nb-Zr pub ICPMS Yokogawa PMS2000 4 20191008105612-912690
JB-1b_S pub HR-ICPMS Finningan, Element 1 20191008141042-854799
JB-1b pub MC-ICP-MS Finnigan, Neptune 1 20191219094725-789741
JB-1b_Cr-Fe-Ni-Cu-Zn pub TIMS Thermo-Fisher MAT262 5 20200130113405-220663
ref-gl-jp1 pub Q-ICPMS Agilent 7500cs 50 20170302124611-535452
JP-1 pub ICPMS Yokogawa PMS2000 22 20191008091429-416093
JP-1_Os-Pt pub ICPMS Thermo-Fisher Element XR 6 20190315111352-886503
JP-1_Re-Os pub TIMS Thermo-Fisher Triton 2 20190313154241-671749
JP-1_TiO2 pub HR-ICPMS Finningan, Element 1 20191008134323-872493
JP-1_FeO pub 1 20191009142516-474524
JP-1 pub ICPMS Yokogawa PMS2000 3 20191008113359-201393
JP-1 pub MC-ICP-MS Finnigan, Neptune 2 20191023150858-436623
JP-1_Li pub ICPMS Yokogawa PMS2000 1 20191015113423-515310
JP-1_Bi-Tl-In-Cd pub Q-ICPMS Agilent 7500cs 4 20191002151233-330475
JP-1_d66Zn pub ICPMS Thermo-Fisher Neptune 1 20191003102339-458610
JP-1_d56Fe pub ICPMS Thermo-Fisher Neptune 1 20191003113551-906961
JP-1_Ni-Co-Fe-Mn-Cr pub ICPMS Thermo-Fisher Neptune 5 20191003145531-083716
JP-1_Ge-As-Se-Te pub Q-ICPMS Agilent 7500cs 4 20191004111800-014469
JP-1_TE-Max2006 pub Q-ICPMS Agilent 7500cs 42 20191021092408-322359
JP-1_Pb-Kuritani2006 pub TIMS Thermo-Fisher MAT261 4 20191021120207-324046
JP-1 pub ICPMS Yokogawa PMS2000 4 20191008105613-631359
JP-1_S pub HR-ICPMS Finningan, Element 1 20191008141042-456644
JP-1_Cr-Ni-Cu-Zn pub HR-ICPMS Finningan, Element 4 20191009100319-996060
JP-1_Pb pub TIMS Thermo-Fisher MAT261 3 20191009104304-125212
JP-1_S (Max, 2012) pub ICPMS Thermo-Fisher Neptune 1 20191223153718-288546
JP-1_Cr-Fe-Ni-Cu-Zn pub TIMS Thermo-Fisher MAT262 5 20200130113406-594443
JP-1_Hf pub MC-ICP-MS Finnigan, Neptune 4 20200130145207-079936
JP-1_Pb pub MC-ICP-MS Finnigan, Neptune 3 20200130150729-784131
JP-1_d7Li pub TIMS Thermo-Fisher MAT261 1 20200210103648-262084
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Allende_d56Fe pub ICPMS Thermo-Fisher Neptune 1 20191003113551-551109
Allende_Ni-Co-Fe-Mn-Cr pub ICPMS Thermo-Fisher Neptune 5 20191003145531-704426
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Allende_S pub HR-ICPMS Finningan, Element 1 20191008141043-872077
Allende#1_TE-Max2006 pub Q-ICPMS Agilent 7500cs 50 20191021102837-449584
Allende #1 pub TIMS Thermo-Fisher MAT261 8 20200219112225-837111
Allende#2_TE-Max2006 pub Q-ICPMS Agilent 7500cs 50 20191021105147-772222
Allende #2 pub TIMS Thermo-Fisher MAT261 8 20200219112225-135266
Allende #1_Cd pub Q-ICPMS Agilent 7500cs 3 20191002155809-650896
Allende #2_Cd pub Q-ICPMS Agilent 7500cs 1 20191002155810-327220
Allende #1-a pub TIMS Thermo-Fisher MAT261 2 20200219112225-970612
Allende #1-b pub TIMS Thermo-Fisher MAT261 2 20200219112225-307579
Allende #2-a pub TIMS Thermo-Fisher MAT261 2 20200219112225-957553
Allende #2-b pub TIMS Thermo-Fisher MAT261 2 20200219112225-818392
name spots global-id
caption ID rowname stone
Table 4. Cr, Mn, Fe, Co and Ni concentrations for silicate reference materials determined by HR–MC–ICP–MS pub 20191003145931-022400 Cr, Mn, Fe, Co, Ni (Max et al., 2010) 3
manual
  • name
  • Akio Makishima
  • Yamakawa, Akane
  • Yamashita, Katsuyuki
  • Eizo Nakamura